Original Article
Copyright ©2013 Baishideng Publishing Group Co., Limited. All rights reserved.
World J Radiol. Nov 28, 2013; 5(11): 411-420
Published online Nov 28, 2013. doi: 10.4329/wjr.v5.i11.411
Magnetically-coated silica nanospheres for dual-mode imaging at low ultrasound frequency
Fernanda Chiriacò, Giulia Soloperto, Antonio Greco, Francesco Conversano, Andrea Ragusa, Luca Menichetti, Sergio Casciaro
Fernanda Chiriacò, Giulia Soloperto, Antonio Greco, Francesco Conversano, Sergio Casciaro, Consiglio Nazionale delle Ricerche, Istituto di Fisiologia Clinica (CNR-IFC) c/o Campus Ecotekne, via per Monteroni, 73100 Lecce, Italy
Andrea Ragusa, National Research Council, Istituto di Nanoscienze, 73100 Lecce, Italy
Luca Menichetti, National Research Council, Institute of Clinical Physiology, 56100 Pisa, Italy
Author contributions: All the authors were involved in designing the study and writing the manuscript; Greco A performed the ultrasound experiments and data acquisition; Conversano F, Soloperto G did the data analysis and contributed to the paper drafting; Chiriacò F was involved in writing and editing the manuscript; Menichetti L, Ragusa A synthetized the dual mode nanoparticles and provided the scanning electron microscopy characterization; Casciaro S conceived and co-ordinated the study.
Supported by Italian Ministry of Instruction and Research, No. DM18604-Bando Laboratori-DD MIUR 14.5.2005 n.602/Ric/2005; by FESR PO Apulia Region 2007-2013-Action 1.2.4, No. 3Q5AX31; and by the Progetto Bandiera NANOMAX ENCODER
Correspondence to: Dr. Sergio Casciaro, Consiglio Nazionale delle Ricerche, Istituto di Fisiologia Clinica (CNR-IFC) c/o Campus Ecotekne, via per Monteroni, 73100 Lecce, Italy. sergio.casciaro@cnr.it
Telephone: +39-832-422310 Fax: +39-832-422341
Received: June 28, 2013
Revised: September 6, 2013
Accepted: October 18, 2013
Published online: November 28, 2013
Processing time: 153 Days and 15.2 Hours
Abstract

AIM: To experimentally investigate the acoustical behavior of different dual-mode nanosized contrast agents (NPCAs) for echographic medical imaging at low ultrasound (US) frequency.

METHODS: We synthesized three different nanosized structures: (1) Pure silica nanospheres (SiNSs); (2) FePt-iron oxide (FePt-IO)-coated SiNSs; and (3) IO-coated SiNSs, employing three different diameter of SiNS-core (160, 330 and 660 nm). Tissue mimicking phantoms made of agarose gel solution containing 5 mg of different NPCAs in 2 mL-Eppendorf tubes, were insonified by a commercial echographic system at three different low US pulse values (2.5, 3.5 and 4.5 MHz). The raw radiofrequency signal, backscattered from each considered NPCA containing sample, has been processed in order to calculate the US average backscatter intensity and compare the acoustic behavior of the different NPCA types.

RESULTS: The highest US contrast was exhibited by pure SiNSs; FePt-IO-coated SiNSs acoustical behavior followed a similar trend of pure SiNSs with a slight difference in terms of brightness values. The acoustic response of the examined NPCAs resulted function of both SiNS diameter and US frequency. Specifically, higher US frequencies determined higher value of the backscatter for a given SiNS diameter. Frequency-dependent enhancement was marked for pure SiNSs and became less remarkable for FePt-IO-coated SiNSs, whereas IO-coated SiNSs resulted almost unaffected by such frequency variations. Pure and FePt-IO-coated SiNSs evidenced an image backscatter increasing with the diameter up to 330 nm. Conversely, among the types of NPCA tested, IO-coated SiNSs showed the lowest acoustical response for each synthesized diameter and employed US frequency, although a diameter-dependent raising trend was evidenced.

CONCLUSION: The US characterization of magnetically covered SiNS shows that FePt-IO, rather than IO, was the best magnetic coating for realizing NPCAs suitable for dual mode imaging of deep organs, combining US and magnetic resonance imaging.

Keywords: Ultrasound; Magnetic resonance; Nanocomposite; Dual-mode Imaging; Contrast agent; Diagnostic imaging

Core tip: In this work we investigated the acoustic response of novel dual-mode nanoparticle contrast agents, detectable through both ultrasound (US) and magnetic resonance imaging (MRI), made of silica nanospheres (SiNSs) of different diameters coated with superparamagnetic nanoparticles [iron-oxide (IO) or FePt-IO nanocrystals]. Magnetically-coated SiNSs were insonified with US pulses in the lower diagnostic range (2.5-4.5 MHz), which are commonly employed for the imaging of deep organs, and the results were compared with those of pure SiNSs. The US characterization of these nanocomposites shows that FePt-IO, rather than IO, was the best magnetic coating for realizing nanosized contrast agents suitable for dual mode imaging of deep targets, combining US and MRI techniques.