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For: Mykhailiuk PK. 2,2,2-Trifluorodiazoethane (CF 3 CHN 2 ): A Long Journey since 1943. Chem Rev 2020;120:12718-55. [DOI: 10.1021/acs.chemrev.0c00406] [Cited by in Crossref: 60] [Cited by in F6Publishing: 63] [Article Influence: 30.0] [Reference Citation Analysis]
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11 Devi L, Kumar P, Kant R, Rastogi N. Exploiting the umpolung reactivity of diazo groups: direct access to triazolyl-azaarenes from azaarenes. Chem Commun (Camb) 2022;58:7062-5. [PMID: 35648386 DOI: 10.1039/d2cc01897g] [Cited by in Crossref: 1] [Cited by in F6Publishing: 1] [Article Influence: 1.0] [Reference Citation Analysis]
12 Liu Z, Sivaguru P, Zanoni G, Bi X. N-Triftosylhydrazones: A New Chapter for Diazo-Based Carbene Chemistry. Acc Chem Res 2022. [PMID: 35675648 DOI: 10.1021/acs.accounts.2c00186] [Cited by in Crossref: 3] [Cited by in F6Publishing: 4] [Article Influence: 3.0] [Reference Citation Analysis]
13 Wang Q, Liu J, Wang N, Pajkert R, Mei H, Röschenthaler G, Han J. One‐Pot Reaction of (β‐Amino‐α,α‐difluoroethyl)phosphonates with Trifluoromethylated Ketones via Aza‐Wittig Reagents. Adv Synth Catal 2022;364:1969-74. [DOI: 10.1002/adsc.202200330] [Cited by in Crossref: 2] [Cited by in F6Publishing: 2] [Article Influence: 2.0] [Reference Citation Analysis]
14 Liu J, Pajkert R, Wang L, Mei H, Röschenthaler G, Han J. Facile synthesis of (β-chlorodifluoroethyl)phosphonates via chlorination reaction of difluoroalkyl diazo derivatives with HCl. Chinese Chemical Letters 2022;33:2429-32. [DOI: 10.1016/j.cclet.2021.10.066] [Cited by in Crossref: 3] [Cited by in F6Publishing: 4] [Article Influence: 3.0] [Reference Citation Analysis]
15 Zhang X, Li L, Zanoni G, Han X, Bi X. Direct gem-Difluoroalkenylation of X-H Bonds with Trifluoromethyl Ketone N-Triftosylhydrazones for Synthesis of Tetrasubstituted Heteroatomic gem-Difluoroalkenes. Chemistry 2022;28:e202200280. [PMID: 35191565 DOI: 10.1002/chem.202200280] [Cited by in Crossref: 2] [Cited by in F6Publishing: 2] [Article Influence: 2.0] [Reference Citation Analysis]
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17 Kowalczyk A, Utecht-Jarzyńska G, Mlostoń G, Jasiński M. Trifluoromethylated Pyrazoles via Sequential (3 + 2)-Cycloaddition of Fluorinated Nitrile Imines with Chalcones and Solvent-Dependent Deacylative Oxidation Reactions. Org Lett 2022. [PMID: 35343703 DOI: 10.1021/acs.orglett.2c00521] [Cited by in Crossref: 4] [Cited by in F6Publishing: 7] [Article Influence: 4.0] [Reference Citation Analysis]
18 Mei H, Wang N, Li Z, Han J. Intramolecular Appel Reaction of Trifluoromethylated β-Keto Diazos Enabling Assembly of Trifluoromethylpyrazoles. Org Lett 2022. [PMID: 35297254 DOI: 10.1021/acs.orglett.2c00738] [Cited by in Crossref: 1] [Cited by in F6Publishing: 3] [Article Influence: 1.0] [Reference Citation Analysis]
19 Lin X, Luo B, He W, Lu Q, Li L, Zheng H, Wu W, Weng Z. Metal-free synthesis of 5-trifluoromethyltetrazoles. Tetrahedron Letters 2022. [DOI: 10.1016/j.tetlet.2022.153717] [Cited by in Crossref: 1] [Cited by in F6Publishing: 1] [Article Influence: 1.0] [Reference Citation Analysis]
20 Gribov PS, Mikhailova MV, Kon'kova TS, Matyushin YN, Sheremetev AB. Di(propargyl)nitramine: synthesis and reactivity. Mendeleev Communications 2022;32:218-20. [DOI: 10.1016/j.mencom.2022.03.021] [Cited by in Crossref: 1] [Cited by in F6Publishing: 3] [Article Influence: 1.0] [Reference Citation Analysis]
21 Qi M, Suleman M, Xie J, Lu P, Wang Y. Cu(II)-Catalyzed Synthesis of 4-(1,4,5,6-Tetrahydropyridin-3-yl)-1,4-dihydroisoquinolin-3-ones from 4-Diazoisoquinolin-3-ones. J Org Chem 2022. [PMID: 35213165 DOI: 10.1021/acs.joc.1c02905] [Cited by in Crossref: 2] [Cited by in F6Publishing: 2] [Article Influence: 2.0] [Reference Citation Analysis]
22 Mykhailiuk PK. Fluorine-Containing Prolines: Synthetic Strategies, Applications, and Opportunities. J Org Chem 2022. [PMID: 35175772 DOI: 10.1021/acs.joc.1c02956] [Cited by in Crossref: 3] [Cited by in F6Publishing: 3] [Article Influence: 3.0] [Reference Citation Analysis]
23 Fang Z, Jin Q, Wang X, Ning Y. Metal-free [2 + 1 + 3] Cycloaddition of Trifluoroacetaldehyde N-Sulfonylhydrazones with Hexahydro-1,3,5-triazines Leading to Trifluoromethylated 2,3,4,5-Tetrahydro-1,2,4-triazines. J Org Chem 2022. [PMID: 35133818 DOI: 10.1021/acs.joc.1c02810] [Cited by in Crossref: 2] [Cited by in F6Publishing: 2] [Article Influence: 2.0] [Reference Citation Analysis]
24 Zhai S, Cahard D, Zhang F, Ma J. Metal-free regioselective construction of 2-aryl-2H-tetrazol-5-yl difluoromethylene phosphonates. Chinese Chemical Letters 2022;33:863-6. [DOI: 10.1016/j.cclet.2021.08.007] [Cited by in Crossref: 4] [Cited by in F6Publishing: 4] [Article Influence: 4.0] [Reference Citation Analysis]
25 Li S, Sun S, Wang J. Catalytic Asymmetric Homologation of 4‐Substituted Cyclohexanones with CF 3 CHN 2 : Enantioselective Synthesis of α Trifluoromethyl Cycloheptanones. Angewandte Chemie 2022;134. [DOI: 10.1002/ange.202115098] [Reference Citation Analysis]
26 Wang J, Liu S, Huang Y, Xu XH, Qing FL. Photoredox catalyzed C-H trifluoroethylamination of heteroarenes. Chem Commun (Camb) 2022;58:1346-9. [PMID: 34986214 DOI: 10.1039/d1cc06688a] [Reference Citation Analysis]
27 Kani R, Inuzuka T, Kubota Y, Funabiki K. Synthesis of 1‐Trifluoromethylated Propargyl Alcohols by Two Successive Reactions of Cyclopentylmagnesium Bromide in a One‐Pot Manner. Asian J of Organic Chemis. [DOI: 10.1002/ajoc.202100700] [Reference Citation Analysis]
28 Chandrasekharan SP, Dhami A, Kumar S, Mohanan K. Recent advances in pyrazole synthesis employing diazo compounds and synthetic analogues. Org Biomol Chem 2022. [DOI: 10.1039/d2ob01918c] [Reference Citation Analysis]
29 Zhang Q, Wang Y, Li S, Wang Y, Wei D. Organocatalytic insertion into C–B bonds by in situ generated carbene: mechanism, role of the catalyst, and origin of stereoselectivity. Catal Sci Technol 2022;12:947-53. [DOI: 10.1039/d1cy01232k] [Cited by in Crossref: 9] [Cited by in F6Publishing: 9] [Article Influence: 9.0] [Reference Citation Analysis]
30 Kumar A, Khan WA, Ahamad S, Mohanan K. Trifluorodiazoethane: A versatile building block to access trifluoromethylated heterocycles. Journal of Heterocyclic Chem. [DOI: 10.1002/jhet.4416] [Reference Citation Analysis]
31 Shi HS, Li SH, Zhang FG, Ma JA. Catalytic regioselective construction of phenylthio- and phenoxyldifluoroalkyl tetrazoles from difluorodiazoketones. Chem Commun (Camb) 2021;57:13744-7. [PMID: 34851338 DOI: 10.1039/d1cc05890h] [Cited by in Crossref: 2] [Cited by in F6Publishing: 2] [Article Influence: 2.0] [Reference Citation Analysis]
32 Li SS, Sun S, Wang J. Catalytic Asymmetric Homologation of 4-Substituted Cyclohexanones with CF3 CHN2 : Enantioselective Synthesis of α-Trifluoromethyl Cycloheptanones. Angew Chem Int Ed Engl 2021;:e202115098. [PMID: 34939732 DOI: 10.1002/anie.202115098] [Cited by in Crossref: 5] [Cited by in F6Publishing: 6] [Article Influence: 5.0] [Reference Citation Analysis]
33 Modak A, Alegre-Requena JV, de Lescure L, Rynders KJ, Paton RS, Race NJ. Homologation of Electron-Rich Benzyl Bromide Derivatives via Diazo C-C Bond Insertion. J Am Chem Soc 2021. [PMID: 34898193 DOI: 10.1021/jacs.1c11503] [Cited by in Crossref: 6] [Cited by in F6Publishing: 6] [Article Influence: 6.0] [Reference Citation Analysis]
34 Zhao WW, Shao YC, Wang AN, Huang JL, He CY, Cui BD, Wan NW, Chen YZ, Han WY. Diazotrifluoroethyl Radical: A CF3-Containing Building Block in [3 + 2] Cycloaddition. Org Lett 2021;23:9256-61. [PMID: 34802247 DOI: 10.1021/acs.orglett.1c03603] [Cited by in Crossref: 1] [Cited by in F6Publishing: 2] [Article Influence: 1.0] [Reference Citation Analysis]
35 Devi L, Pokhriyal A, Shekhar S, Kant R, Mukherjee S, Rastogi N. Organo‐photocatalytic Synthesis of 6‐ β ‐Disubstituted Phenanthridines from α ‐Diazo‐ β‐ Keto Compounds and Vinyl Azides. Asian J Org Chem 2021;10:3328-3333. [DOI: 10.1002/ajoc.202100518] [Cited by in Crossref: 1] [Cited by in F6Publishing: 1] [Article Influence: 1.0] [Reference Citation Analysis]
36 Zheng Y, Moegle B, Ghosh S, Perfetto A, Luise D, Ciofini I, Miesch L. Copper-Catalyzed Synthesis of Terminal vs. Fluorine-Substituted N-Allenamides via Addition of Diazo Compounds to Terminal Ynamides. Chemistry 2021. [PMID: 34826155 DOI: 10.1002/chem.202103598] [Cited by in Crossref: 1] [Cited by in F6Publishing: 1] [Article Influence: 1.0] [Reference Citation Analysis]
37 Zhang X, Sivaguru P, Zanoni G, Han X, Tong M, Bi X. Catalytic Asymmetric C(sp 3 )–H Carbene Insertion Approach to Access Enantioenriched 3-Fluoroalkyl 2,3-Dihydrobenzofurans. ACS Catal 2021;11:14293-301. [DOI: 10.1021/acscatal.1c04523] [Cited by in Crossref: 7] [Cited by in F6Publishing: 7] [Article Influence: 7.0] [Reference Citation Analysis]
38 Noonikara-Poyil A, Muñoz-Castro A, Boretskyi A, Mykhailiuk PK, Dias HVR. When SF5 outplays CF3: effects of pentafluorosulfanyl decorated scorpionates on copper. Chem Sci 2021;12:14618-23. [PMID: 34881014 DOI: 10.1039/d1sc04846e] [Cited by in Crossref: 11] [Cited by in F6Publishing: 10] [Article Influence: 11.0] [Reference Citation Analysis]
39 Wang Q, Wang L, Pajkert R, Hajdin I, Mei H, Röschenthaler G, Han J. [3+2] Cycloaddition reactions of β-diazo-α,α-difluoromethylphosphonates with α,β-unsaturated esters. Journal of Fluorine Chemistry 2021;251:109899. [DOI: 10.1016/j.jfluchem.2021.109899] [Cited by in Crossref: 2] [Cited by in F6Publishing: 3] [Article Influence: 2.0] [Reference Citation Analysis]
40 Sivaguru P, Bi X. Fluoroalkyl N-sulfonyl hydrazones: An efficient reagent for the synthesis of fluoroalkylated compounds. Sci China Chem 2021;64:1614-29. [DOI: 10.1007/s11426-021-1052-7] [Cited by in Crossref: 7] [Cited by in F6Publishing: 6] [Article Influence: 7.0] [Reference Citation Analysis]
41 Su Y, Dong K, Zheng H, Doyle MP. Generation of Diazomethyl Radicals by Hydrogen Atom Abstraction and Their Cycloaddition with Alkenes. Angew Chem 2021;133:18632-6. [DOI: 10.1002/ange.202105472] [Cited by in Crossref: 1] [Cited by in F6Publishing: 1] [Article Influence: 1.0] [Reference Citation Analysis]
42 Ramirez NP, Pisella G, Waser J. Cu(I)-Catalyzed gem-Aminoalkynylation of Diazo Compounds: Synthesis of Fluorinated Propargylic Amines. J Org Chem 2021;86:10928-38. [PMID: 34260244 DOI: 10.1021/acs.joc.1c01423] [Cited by in Crossref: 1] [Cited by in F6Publishing: 1] [Article Influence: 1.0] [Reference Citation Analysis]
43 Wang Y, Mu S, Li X, Song Q. [4+1] cyclization of benzohydrazide and ClCF2COONa towards 1,3,4-oxadiazoles and 1,3,4-oxadiazoles-d5. Chinese Chemical Letters 2021. [DOI: 10.1016/j.cclet.2021.08.089] [Cited by in Crossref: 9] [Cited by in F6Publishing: 9] [Article Influence: 9.0] [Reference Citation Analysis]
44 Chen YJ, Zhang FG, Ma JA. Zinc-Enabled Annulation of Trifluorodiazoethane with 2H-Azirines to Construct Trifluoromethyl Pyrazolines, Pyrazoles, and Pyridazines. Org Lett 2021;23:6062-6. [PMID: 34319752 DOI: 10.1021/acs.orglett.1c02139] [Cited by in Crossref: 11] [Cited by in F6Publishing: 12] [Article Influence: 11.0] [Reference Citation Analysis]
45 Kumar A, Dhami A, Fairoosa J, Kant R, Mohanan K. Silver-Catalyzed Direct Synthesis of Trifluoromethylated Enaminopyridines and Isoquinolinones Employing Trifluorodiazoethane. Org Lett 2021;23:5815-20. [PMID: 34264078 DOI: 10.1021/acs.orglett.1c01969] [Cited by in Crossref: 6] [Cited by in F6Publishing: 6] [Article Influence: 6.0] [Reference Citation Analysis]
46 Su YL, Dong K, Zheng H, Doyle MP. Generation of Diazomethyl Radicals by Hydrogen Atom Abstraction and Their Cycloaddition with Alkenes. Angew Chem Int Ed Engl 2021;60:18484-8. [PMID: 34043866 DOI: 10.1002/anie.202105472] [Cited by in Crossref: 8] [Cited by in F6Publishing: 8] [Article Influence: 8.0] [Reference Citation Analysis]
47 Zhang X, Tian C, Wang Z, Sivaguru P, Nolan SP, Bi X. Fluoroalkyl N -Triftosylhydrazones as Easily Decomposable Diazo Surrogates for Asymmetric [2 + 1] Cycloaddition: Synthesis of Chiral Fluoroalkyl Cyclopropenes and Cyclopropanes. ACS Catal 2021;11:8527-37. [DOI: 10.1021/acscatal.1c01483] [Cited by in Crossref: 12] [Cited by in F6Publishing: 13] [Article Influence: 12.0] [Reference Citation Analysis]
48 Cao T, Yang Z, Sun Y, Zhao N, Lu S, Zhang J, Wang L. Lewis Base‐Catalyzed Cycloaddition of Heterocyclic Alkenes with 2,2,2‐Trifluorodiazoethane (CF 3 CHN 2 ): Access to Trifluoromethylated Pyrazolines and Pyrazoles. Eur J Org Chem 2021;2021:2950-4. [DOI: 10.1002/ejoc.202100521] [Cited by in Crossref: 4] [Cited by in F6Publishing: 4] [Article Influence: 4.0] [Reference Citation Analysis]
49 Ren S, Xu G, Guo Y, Liu Q, Guo C. Iron porphyrin-catalyzed N-trifluoroethylation of anilines with 2,2,2-trifluoroethylamine hydrochloride in aqueous solution. RSC Adv 2021;11:20322-5. [PMID: 35479926 DOI: 10.1039/d1ra03379d] [Cited by in Crossref: 3] [Cited by in F6Publishing: 3] [Article Influence: 3.0] [Reference Citation Analysis]
50 Kumar A, Jamali MF, Thomas S, Ahamad S, Kant R, Mohanan K. Additive‐Free Synthesis of Trifluoromethylated Spiro Cyclopropanes and Their Transformation into Trifluoromethylated Building Blocks. Asian J of Organic Chemis 2021;10:1536-41. [DOI: 10.1002/ajoc.202100207] [Cited by in Crossref: 1] [Cited by in F6Publishing: 1] [Article Influence: 1.0] [Reference Citation Analysis]
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52 Wan C, Pang JY, Jiang W, Zhang XW, Hu XG. Copper-Catalyzed Reductive Ring-Cleavage of Isoxazoles: Synthesis of Fluoroalkylated Enaminones and Application for the Preparation of Celecoxib, Deracoxib, and Mavacoxib. J Org Chem 2021;86:4557-66. [PMID: 33586981 DOI: 10.1021/acs.joc.0c02980] [Cited by in Crossref: 8] [Cited by in F6Publishing: 8] [Article Influence: 8.0] [Reference Citation Analysis]
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54 Tian Y, Li J, Zhang F, Ma J. Regioselective Decarboxylative Cycloaddition Route to Fully Substituted 3‐CF 3 ‐Pyrazoles from Nitrilimines and Isoxazolidinediones. Adv Synth Catal 2021;363:2093-7. [DOI: 10.1002/adsc.202100091] [Cited by in Crossref: 6] [Cited by in F6Publishing: 7] [Article Influence: 6.0] [Reference Citation Analysis]
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56 Mei H, Wang L, Pajkert R, Wang Q, Xu J, Liu J, Röschenthaler GV, Han J. In Situ Generation of Unstable Difluoromethylphosphonate-Containing Diazoalkanes and Their Use in [3 + 2] Cycloaddition Reactions with Vinyl Sulfones. Org Lett 2021;23:1130-4. [PMID: 33480704 DOI: 10.1021/acs.orglett.1c00150] [Cited by in Crossref: 8] [Cited by in F6Publishing: 10] [Article Influence: 8.0] [Reference Citation Analysis]
57 Mei H, Liu J, Pajkert R, Wang L, Röschenthaler G, Han J. Design of (β-diazo-α,α-difluoroethyl)phosphonates and their application as masked carbenes in visible light-promoted coupling reactions with sulfonic acids. Org Chem Front 2021;8:767-72. [DOI: 10.1039/d0qo01394c] [Cited by in Crossref: 9] [Cited by in F6Publishing: 12] [Article Influence: 9.0] [Reference Citation Analysis]
58 Liu J, Xu J, Pajkert R, Mei H, Röschenthaler G, Han J. Esterification of Carboxylic Acids with (β-Diazo-α,α-difluoroethyl)phosphonates under Photochemical Conditions. Acta Chimica Sinica 2021;79:747. [DOI: 10.6023/a21030096] [Cited by in Crossref: 7] [Cited by in F6Publishing: 10] [Article Influence: 7.0] [Reference Citation Analysis]
59 Suleman M, Lu P, Wang Y. Recent advances in the synthesis of indole embedded heterocycles with 3-diazoindolin-2-imines. Org Chem Front 2021;8:2059-78. [DOI: 10.1039/d0qo01515f] [Cited by in Crossref: 16] [Cited by in F6Publishing: 19] [Article Influence: 16.0] [Reference Citation Analysis]
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